Quick Review of Chemistry Related to the [Fe]-Hydrogenases

This review provides a comprehensive overview of the synthesis, reactivity, and electrochemistry chemical models active site structures in [Fe] hydrogenase, an enzyme that catalyzes reversible reduction protons to submergence. Related literature on structure functions hydrogenase site, H cluster, is discussed with emphasis di-iron organosome. In addition, various methods for preparation characterization model complexes are discussed, as well reactivity studies focusing oxidation compounds their interaction small molecules such hydrogen carbon monoxide. Finally, electrochemical behavior relation performance electrocatalytic applications. analysis chemistry which can be valuable reference further research.